http://www.dotabuff.com/pages/faq
click Update match history.
it should be there after a couple of minutes
if its not on the list in his recent dota matches inside dota 2 client, then "update match history" wont help, since this game is not recorded initially (probably due to someone abandoning it before fb, or idk)
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My last game was 7 hours ago ,with spectre but dotabuff and DotA didn't count it, how this could be possible?